Adhikary, Jaydeep and Banerjee, Priyabrata and Chattopadhyay, Tanmay (2015) Alumina-supported Mn(III) and Fe(III) complexes of tridentate Schiff base ligand having ONO-donor sites: Syntheses, characterization and olefin epoxidation study. Indian Journal of Chemistry -Section A , 54A (10). pp. 1175-1182.

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Two new mononuclear Schiff base complexes, [MLCl(H2O)2] [M = Mn(III) or Fe(III); H2L = 2-phenoliminomethylphenol], have been prepared and characterized by elemental analysis, thermogravimetric analysis, UV-vis and FT-IR spectroscopy, cyclic voltammetry and ESI-MS analyses. Both complexes show excellent alkenes epoxidation activity and thus these complexes have been infused over neutral active alumina to prepare the heterogeneous catalysts. These catalysts are characterized by solid UV-vis and FT-IR spectroscopy, thermogravimetric and powder XRD and FE-SEM studies. Finally, the catalysts have been studied for the epoxidation of different types of olefins in presence of terminal oxidants (PhIO and t-BHP) and are easily recyclable.

Item Type: Article
Subjects: Chemistry
Depositing User: Dr. Sarita Ghosh
Date Deposited: 08 Jul 2016 09:00
Last Modified: 08 Jul 2016 09:00

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