Chatterjee, Debabrata (2012) Mechanism of -O–O- bond activation and catalysis by RuIII-pac complexes (pac = polyaminocarboxylate). Journal of Chemical Sciences, 124 (6). pp. 1145-1150.

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Abstract

This paper presents the mechanistic aspects of the -O–O- bond activation by the Ru-pac (pac = polyaminocarboxylate) complex leading to the formation of various catalytic active species, viz. [RuIII(pac)(OOH)]2 − , [RuIV(pac)(OH)] −  and [RuV(pac)(O)] − , and their reactivity towards oxidation of a few organic compounds.

Item Type: Article
Subjects: Chemistry
Depositing User: Dr. Sarita Ghosh
Date Deposited: 21 Sep 2016 05:30
Last Modified: 21 Sep 2016 05:30
URI: http://cmeri.csircentral.net/id/eprint/284

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