Chatterjee, Debabrata and Shome, Sanchari and Jaiswal, Namita and Banerjee, Priyabrata (2014) Nitrite reduction mediated by the complex RuIII(EDTA). Dalton Transactions, 43 (36). pp. 13596-13600.

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Abstract

Reported is the first example of a ruthenium(III)-complex, RuIII(EDTA) (EDTA4− = ethylenediaminetetraacetate), that mediates O-atom transfer from nitrite to the biological thiols cysteine and glutathione, leading to the formation of [RuIII(EDTA)(NO+)]0. However, at pH below 5.0, the coordinated nitrite ion in the [RuIII(EDTA)(NO2)]2− complex undergoes proton-assisted decomposition, resulting in the formation of a [RuIII(EDTA)(NO+)]0 species.

Item Type:	Article
Subjects:	Chemistry
Depositing User:	Dr. Sarita Ghosh
Date Deposited:	22 Sep 2016 10:59
Last Modified:	22 Sep 2016 10:59
URI:	http://cmeri.csircentral.net/id/eprint/333

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