Ghosh, Pritam and Hazra, Abhijit and Ghosh, Meenakshi and Murmu, Naresh Chandra and Banerjee, Priyabrata (2018) Halide salts and their structural properties in presence of secondary amine based molecule: A combined experimental and theoretical analysis. Journal of Molecular Structure, 1157. pp. 444-449.

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Abstract

Biologically relevant halide salts and its solution state structural properties are always been significant. In general, exposure of halide salts into polar solution medium results in solvation which in turn separates the cationic and anionic part of the salt. However, the conventional behaviour of salts might alter in presence of any secondary amine based compound, i.e.; moderately strong Lewis acid. In its consequence, to investigate the effect of secondary amine based compound in the salt solution, novel (E)-2-(4-bromobenzylidene)-1-(perfluorophenyl) hydrazine has been synthesized and used as secondary amine source. The secondary amine compound interestingly shows a drastic color change upon exposure to fluoride salts owing to hydrogen bonding interaction. Several experimental methods, e.g.; SCXRD, UV–Vis, FT-IR, ESI-MS and DLS together with modern DFT (i.e.; DFT-D3) have been performed to explore the structural properties of the halide salts upon exposure to secondary amine based compound. The effect of counter cation of the fluoride salt in binding with secondary amine source has also been investigated.

Item Type:	Article
Subjects:	Chemistry
Depositing User:	Dr. Arup Kr. Nandi
Date Deposited:	09 Jul 2020 12:37
Last Modified:	09 Jul 2020 12:37
URI:	http://cmeri.csircentral.net/id/eprint/542

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